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Heat Pump

A heat pump is a machine or device that effectively "moves" thermal energy from one location called the

"source," which is at a lower temperature, to another location called the "sink" or "heat sink", which is

at a higher temperature. An air conditioner is a particular type of heat pump, but the class includes

many other types of devices. During the operation, some of the thermal energy must be transformed to

another type of energy in the process, before reappearing as thermal energy in the sink.

The heat pump uses mechanical work, or some source of thermodynamic work (such as much higher-temperature

heat source dissipating heat to lower temperatures) to accomplish the desired transfer of thermal energy

from source to sink.[1] In the classical thermodynamic sense, a heat pump does not actually move heat,

which by definition cannot flow from cold to hot temperatures. However, since the effect of the device in

moving thermal energy is the same as if heat were flowing (albeit in the incorrect direction with regard

to temperature difference), the "heat pump" is named by analogy.

A heat pump always moves thermal energy in the opposite direction from temperature, but a heat pump that

maintains a thermally conditioned-space can be used to provide either heating or cooling, depending upon

whether the environment is cooler or warmer than the conditioned-space. When pumps are used to provide

heating, they are used because less input from a commercial-energy source is required than is required

for newly-creating thermal energy by transforming heat-free sources of energy (for example, electricity)

or low-entropy sources of energy (for example, a gas flame) directly into the required heating. This is

because the heat pump utilizes some thermal energy from the environment for part of the delivered-

heating, increasing the "efficiency" of the process. In cooler climates, it is common for heat pumps to

be designed only to provide heating.

Even when a heat pump is used for heating, it still uses the same basic refrigeration cycle to do the job

(merely changing operation so that the warm end of the device is inside). Rather than physically turn the

device around, a reversible-cycle heat pump simply operates in a way that changes which coil is the

condenser, and which the evaporator. This is normally achieved by a "reversing valve." Common examples of

non-reversible (unidirectional) heat pumps are air conditioners, food refrigerators, and freezers.

Reversible-cycle heat pumps are often seen in providing building-space heating in high latitude climates

that are much warmer than comfortable in one season, but colder in another season. In heating,

ventilation, and air conditioning (HVAC) applications, the term heat pump normally refers to a vapor-

compression refrigeration device that includes a reversing valve and optimized heat exchangers so that

the direction of thermal energy flow may be changed without loss of efficiency. Most commonly, when used

in heating, heat pumps draw heat from the air or from the ground.[2]

Contents

1 Overview
1.1 Operating principles
1.2 Heat sources
1.3 Applications
2 Refrigerants
3 Efficiency
3.1 COP and lift
4 Types
5 Heat sources
5.1 Air-source heat pumps
5.1.1 Air source heat pumps for cold climates
5.2 Ground source heat pumps
5.3 Heat distribution
5.4 Solid state heat pumps
6 History
7 See also
8 References
9 External links
Overview

Heat pumps have the ability to move thermal energy from one environment to another, and in either

direction. This allows the heat pump to effectively bring thermal energy into an occupied space, or to

take it out. In practice, this is always done in the opposite direction of a temperature gradient. A heat

pump works in the same manner as an ordinary air conditioner (A/C), which itself is a type of heat pump.

In the warming mode for a space, a heat pump effectively reverses a refrigeration unit so that the warm

radiator is inside the space, rather than outside.

In classical thermodynamics, heat is defined as a movement of energy in the direction of a thermal

gradient, and in this strict sense a "heat pump" is misnamed, since by definition, classical heat cannot

be moved or pumped from colder to warmer temperatures. In fact, some of the energy moved by heat pumps is

moved in the form of thermodynamic work, and often mechanical work (a narrower definition of work), and

not as heat. However, since the effect is somewhat the same (thermal energy disappears in one place and

reappears in another), the device gained its name by loose analogy.

A heat pump uses an intermediate fluid called a refrigerant which absorbs heat as it vaporizes and

releases the heat when it is condensed. It uses an evaporator to absorb heat from inside an occupied

space and rejects this heat to the outside through the condenser. The refrigerant flows outside of the

space to be conditioned, where the condenser and compressor are located, while the evaporator is inside.

The key component that makes a heat pump different from an air conditioner is the reversing valve. The

reversing valve allows for the flow direction of the refrigerant to be changed. This allows the heat to

be pumped in either direction.

In heating mode the outdoor coil becomes the evaporator, while the indoor becomes the condenser which

absorbs the heat from the refrigerant and dissipates to the air flowing through it. The air outside even

at 0 °C (or at any temperature above absolute zero) has heat energy in it. With the refrigerant flowing

in the opposite direction the evaporator (outdoor coil) is absorbing the heat from the air and moving it

inside. Once it picks up heat it is compressed and then sent to the condenser (indoor coil). The indoor

coil then injects the heat into the air handler, which moves the heated air throughout the house.
In cooling mode the outdoor coil is now the condenser. This makes the indoor coil now the evaporator. The

indoor coil is now the evaporator in the sense that it is going to be used to absorb the heat from inside

the enclosed space. The evaporator absorbs the heat from the inside, and takes it to the condenser where

it is rejected into the outside air.
Operating principles

Since the heat pump or refrigerator uses a certain amount of work to move the refrigerant, the amount of

energy deposited on the hot side is greater than taken from the cold side. One common type of heat pump

works by exploiting the physical properties of a volatile evaporating and condensing fluid known as a

refrigerant.

 

A simple stylized diagram of a heat pump's vapor-compression refrigeration cycle: 1) condenser, 2)

expansion valve, 3) evaporator, 4) compressor.
The working fluid, in its gaseous state, is pressurized and circulated through the system by a

compressor. On the discharge side of the compressor, the now hot and highly pressurized vapor is cooled

in a heat exchanger, called a condenser, until it condenses into a high pressure, moderate temperature

liquid. The condensed refrigerant then passes through a pressure-lowering device also called a metering

device like an expansion valve, capillary tube, or possibly a work-extracting device such as a turbine.

The low pressure, liquid refrigerant leaving the expansion device enters another heat exchanger, the

evaporator, in which the fluid absorbs heat and boils. The refrigerant then returns to the compressor and

the cycle is repeated.

In such a system it is essential that the refrigerant reach a sufficiently high temperature when

compressed, since the second law of thermodynamics prevents heat from flowing from a cold fluid to a hot

heat sink. Practically, this means the refrigerant must reach a temperature greater than the ambient

around the high-temperature heat exchanger. Similarly, the fluid must reach a sufficiently low

temperature when allowed to expand, or heat cannot flow from the cold region into the fluid, i.e. the

fluid must be colder than the ambient around the cold-temperature heat exchanger. In particular, the

pressure difference must be great enough for the fluid to condense at the hot side and still evaporate in

the lower pressure region at the cold side. The greater the temperature difference, the greater the

required pressure difference, and consequently the more energy needed to compress the fluid. Thus as with

all heat pumps, the Coefficient of Performance (amount of heat moved per unit of input work required)

decreases with increasing temperature difference.

Insulation is used to reduce the work and energy required to achieve and maintain a lower temperature in

the cooled space.

Due to the variations required in temperatures and pressures, many different refrigerants are available.

Refrigerators, air conditioners, and some heating systems are common applications that use this

technology.

Heat sources

Many heat pumps also use an auxiliary heat source for heating mode. This means that, even though the heat

pump is the primary source of heat, another form is available as a back-up. Electricity, oil, or gas are

the most common sources. This is put in place so that if the heat pump fails or can't provide enough

heat, the auxiliary heat will kick on to make up the difference.

Geothermal heat pumps use shallow ground (which is often at a constant temperature not too far below

"shirt-sleeve temperature") as a heat source and sink, and water as the heat transport medium. They work

in the same manner as an air-to-air heat pump, but instead of indoor and outdoor coils they use water

pumped through earth materials as a heat transfer medium. These are environmentally-friendly and a

cheaper alternative in the long run due to lower operating cost.

Solar Assisted Heat Pumps use thermal waste energy from water source heating and cooling systems as

"fuel" for a Thermal HVAC system. This is a new technology which uses the energy from the water in

holding tanks and a refrigerant to water heat exchange system. The tanks serve as thermal flywheels and

thermal buffers, as needed. In this configuration, the water in the middle tank serves as the “fuel”

for the system. This fuel is pumped into the cold heat exchanger where the heat in the water is extracted

and transferred to warm up the cold refrigerant. The cold water is then pumped into the cold tank. On the

opposite side, the hot water is heated by way of the hot heat exchanger and the heated water is put back

into the hot tank to either be rejected or used further in other heat exchange processes. In most cases

water returns from the zone where work is being done to the neutral tank .[3]

Applications

In HVAC applications, a heat pump is typically a vapor-compression refrigeration device that includes a

reversing valve and optimized heat exchangers so that the direction of heat flow may be reversed. The

reversing valve switches the direction of refrigerant through the cycle and therefore the heat pump may

deliver either heating or cooling to a building. In the cooler climates the default setting of the

reversing valve is heating. The default setting in warmer climates is cooling. Because the two heat

exchangers, the condenser and evaporator, must swap functions, they are optimized to perform adequately

in both modes. As such, the efficiency of a reversible heat pump is typically slightly less than two

separately optimized machines.

In plumbing applications, a heat pump is sometimes used to heat or preheat water for swimming pools or

domestic water heaters.

In somewhat rare applications, both the heat extraction and addition capabilities of a single heat pump

can be useful, and typically results in very effective use of the input energy. For example, when an air

cooling need can be matched to a water heating load, a single heat pump can serve two useful purposes.

That is, a heat pump domestic water heater located in the living area of a home could cool the home,

reducing or eliminating the need for additional air conditioning. This installation would be best-suited

to a climate that is warm or hot most of the year.

Refrigerants

Until the 1990s, the refrigerants were often chlorofluorocarbons such as R-12 (dichlorodifluoromethane),

one in a class of several refrigerants using the brand name Freon, a trademark of DuPont. Its manufacture

was discontinued in 1995 because of the damage that CFCs cause to the ozone layer if released into the

atmosphere. One widely adopted replacement refrigerant is the hydrofluorocarbon (HFC) known as R-134a

(1,1,1,2-tetrafluoroethane). R-134a is not as efficient as the R-12 it replaced (in automotive

applications) and therefore, more energy is required to operate systems utilizing R-134a than those using

R-12. Other substances such as liquid R-717 ammonia are widely used in large-scale systems, or

occasionally the less corrosive but more flammable propane or butane, can also be used.

Since 2001, carbon dioxide, R-744, has increasingly been used, utilizing the transcritical cycle. In

residential and commercial applications, the hydrochlorofluorocarbon (HCFC) R-22 is still widely used,

however, HFC R-410A does not deplete the ozone layer and is being used more frequently. Hydrogen, helium,

nitrogen, or plain air is used in the Stirling cycle, providing the maximum number of options in

environmentally friendly gases.

More recent refrigerators are now exploiting the R600A which is isobutane, and does not deplete the ozone

and is friendly to the environment.

Dimethyl ether (DME) is also gaining popularity as a refrigerant.[4]

Efficiency

When comparing the performance of heat pumps, it is best to avoid the word "efficiency" which has a very

specific thermodynamic definition. The term coefficient of performance (COP) is used to describe the

ratio of useful heat movement to work input. Most vapor-compression heat pumps use electrically powered

motors for their work input. However, in most vehicle applications, shaft work, via their internal

combustion engines, provide the needed work.

When used for heating a building on a mild day of say 10 °C, a typical air-source heat pump has a COP of

3 to 4, whereas a typical electric resistance heater has a COP of 1.0. That is, one joule of electrical

energy will cause a resistance heater to produce one joule of useful heat, while under ideal conditions,

one joule of electrical energy can cause a heat pump to move much more than one joule of heat from a

cooler place to a warmer place.

Note that the heat pump is more efficient on average in hotter climates than cooler ones, so when the

weather is much warmer the unit will perform better than average COP. Conversely in cold weather the COP

approaches 1. Thus when there is a wide temperature differential between the hot & cold reservoirs the

COP is lower (worse).

When there is a high temperature differential on a cold day, e.g., when an air-source heat pump is used

to heat a house on a very cold winter day of say 0 °C, it takes more work to move the same amount of

heat indoors than on a mild day. Ultimately, due to Carnot efficiency limits, the heat pump's performance

will approach 1.0 as the outdoor-to-indoor temperature difference increases for colder climates

(temperature gets colder). This typically occurs around −18 °C (0 °F) outdoor temperature for air

source heat pumps. Also, as the heat pump takes heat out of the air, some moisture in the outdoor air may

condense and possibly freeze on the outdoor heat exchanger. The system must periodically melt this ice.

In other words, when it is extremely cold outside, it is simpler, and wears the machine less, to heat

using an electric-resistance heater than to strain an air-source heat pump.

Geothermal heat pumps, on the other hand, are dependent upon the temperature underground, which is "mild"

(typically 10 °C at a depth of more than 1.5m for the UK) all year round. Their COP is therefore

normally in the range of 4.0 to 5.0.

The design of the evaporator and condenser heat exchangers is also very important to the overall

efficiency of the heat pump. The heat exchange surface areas and the corresponding temperature

differential (between the refrigerant and the air stream) directly affect the operating pressures and

hence the work the compressor has to do in order to provide the same heating or cooling effect. Generally

the larger the heat exchanger the lower the temperature differential and the more efficient the system.

Heat exchangers are expensive, requiring drilling for some heat-pump types or large spaces to be

efficient, and the heat pump industry generally competes on price rather than efficiency, as it is

already at a price disadvantage when it comes to initial investment (not long-term savings) compared to

conventional heating solutions like boilers, so the drive towards more efficient heat pumps and air

conditioners is often led by legislative measures on minimum efficiency standards.[5]

In cooling mode a heat pump's operating performance is described as its energy efficiency ratio (EER) or

seasonal energy efficiency ratio (SEER), and both measures have units of BTU/(h·W) (1 BTU/(h·W) = 0.293

W/W). A larger EER number indicates better performance. The manufacturer's literature should provide both

a COP to describe performance in heating mode and an EER or SEER to describe performance in cooling mode.

Actual performance varies, however, and depends on many factors such as installation, temperature

differences, site elevation, and maintenance.

Heat pumps are more effective for heating than for cooling if the temperature difference is held equal.

This is because the compressor's input energy is largely converted to useful heat when in heating mode,

and is discharged along with the moved heat via the condenser. But for cooling, the condenser is normally

outdoors, and the compressor's dissipated work is rejected rather than put to a useful purpose.

For the same reason, opening a food refrigerator or freezer heats up the room rather than cooling it

because its refrigeration cycle rejects heat to the indoor air. This heat includes the compressor's

dissipated work as well as the heat removed from the inside of the appliance.

The COP for a heat pump in a heating or cooling application, with steady-state operation, is:

 

where

ΔQcool is the amount of heat extracted from a cold reservoir at temperature Tcool,
ΔQhot is the amount of heat delivered to a hot reservoir at temperature Thot,
ΔA is the compressor's dissipated work.
All temperatures are absolute temperatures usually measured in kelvins (K).
COP and lift

The COP increases as the temperature difference, or "lift", decreases between heat source and

destination. The COP can be maximised at design time by choosing a heating system requiring only a low

final water temperature (e.g. underfloor heating), and by choosing a heat source with a high average

temperature (e.g. the ground). Domestic hot water (DHW) and radiators require high water temperatures,

affecting the choice of heat pump technology.

Pump type and source Typical use case COP variation with output temperature
35 °C
(e.g. heated screed floor) 45 °C
(e.g. heated screed floor) 55 °C
(e.g. heated timber floor) 65 °C
(e.g. radiator or DHW) 75 °C
(e.g. radiator and DHW) 85 °C
(e.g. radiator and DHW)
High-efficiency air source heat pump (ASHP). Air at −20 °C[6] 2.2 2.0 ‐ ‐

‐ ‐
Two-stage ASHP air at −20 °C[7] Low source temp. 2.4 2.2 1.9 ‐ ‐


High efficiency ASHP air at 0 °C[6] Low output temp. 3.8 2.8 2.2 2.0 ‐


Prototype transcritical CO2 (R744) heat pump with tripartite gas cooler, source at 0 °C[8] High

output temp. 3.3 ‐ ‐ 4.2 ‐ 3.0
Ground source heat pump (GSHP). Water at 0 °C[6] 5.0 3.7 2.9 2.4 ‐


GSHP ground at 10 °C[6] Low output temp. 7.2 5.0 3.7 2.9 2.4 ‐
Theoretical Carnot cycle limit, source −20 °C 5.6 4.9 4.4 4.0 3.7 3.4
Theoretical Carnot cycle limit, source 0 °C 8.8 7.1 6.0 5.2 4.6 4.2
Theoretical Lorentzen cycle limit (CO2 pump), return fluid 25 °C, source 0 °C[8] 10.1

8.8 7.9 7.1 6.5 6.1
Theoretical Carnot cycle limit, source 10 °C 12.3 9.1 7.3 6.1 5.4 4.8
One conclusion is that while current 'best practice' heat pumps (ground source system, operating between

0 and 35 Celsius) have a COP of normally around 4, no better than 5, the maximum achievable is (see under

Carnot-cycle) 12. This means that in the coming decades, the energy efficiency of top-end heat pumps is

likely to at least double. Cranking up efficiency requires the development of a better gas compressor,

fitting HVAC machines with larger heat exchangers with slower gas flows, and solving internal lubrication

problems resulting from slower gas flow.

Types

The two main types of heat pumps are compression heat pumps and absorption heat pumps. Compression heat

pumps always operate on mechanical energy (through electricity), while absorption heat pumps may also run

on heat as an energy source (through electricity or burnable fuels).[9] An absorption heat pump may be

fueled by natural gas or LP gas, for example. While the Gas Utilization Efficiency in such a device,

which is the ratio of the energy supplied to the energy consumed, may average only 1.5; that is better

than a natural gas or LP gas furnace, which can only approach 1. Although an absorption heat pump may not

be as efficient as an electric compression heat pump, an absorption heat pump fueled by natural gas may

be advantageous in locations where electricity is relatively expensive and natural gas is relatively

inexpensive. A natural gas-fired absorption heat pump might also avoid the cost of an electrical service

upgrade which is sometimes necessary for an electric heat pump installation. In the case of air-to-air

heat pumps, an absorption heat pump might also have an advantage in colder regions, due to a lower

minimum operating temperature.ROBUR heat pumps comparison

A number of sources have been used for the heat source for heating private and communal buildings.[10]

air source heat pump (extracts heat from outside air)
air–air heat pump (transfers heat to inside air)
air–water heat pump (transfers heat to a heating circuit and a tank of domestic hot water)
exhaust air heat pump (extracts heat from the exhaust air of a building, requires mechanical ventilation)
exhaust air - water heat pump (transfers heat to a heating circuit and a tank of domestic hot water)
geothermal heat pump (extracts heat from the ground or similar sources)
geothermal–air heat pump (transfers heat to inside air)
ground–air heat pump (ground as a source of heat)
rock–air heat pump (rock as a source of heat)
water–air heat pump (body of water as a source of heat)
geothermal–water heat pump (transfers heat to a heating circuit and a tank of domestic hot water)
ground–water heat pump (ground as a source of heat)
rock–water heat pump (rock as a source of heat)
water–water heat pump (body of water as a source of heat)
hybrid (or twin source) heat pumps: when outdoor air is above 4 to 8 Celcius, (40-50 Fahrenheit,

depending on ground water temperature) they use air, when air is colder, they use the ground source.

These twin source systems can also store summer heat, by running ground source water through the air

exchanger or through the building heater-exchanger, even when the heat pump itself is not running. This

has dual advantage: it functions as a low running cost for air cooling, and (if ground water is

relatively stagnant) it cranks up the temperature of the ground source, which improves the energy

efficiency of the heat pump system by roughly 4 percent for each degree in temperature rise of the ground

source.
Heat sources

By definition, all heat sources for a heat pump must be colder in temperature than the space to be

heated. Most commonly, heat pumps draw heat from the air (outside or inside air) or from the ground

(groundwater or soil).[11] The heat drawn from the ground is in most cases stored solar heat, and it

should not be confused with direct geothermal heating, though the latter will contribute in some small

measure to all heat in the ground. Geothermal heat, when used for heating, requires a circulation pump

but no heat pump, since for this technology the ground temperature is higher than that of the space that

is to be heated, so the technology relies only upon simple heat convection. Other heat sources for heat

pumps include water; nearby streams and other natural water bodies have been used, and sometimes domestic

waste water (via drain water heat recovery) which is often warmer than cold winter ambient temperatures

(though still of lower temperature than the space to be heated).

Air-source heat pumps

Air source heat pumps are relatively easy (and inexpensive) to install and have therefore historically

been the most widely used heat pump type. However, they suffer limitations due to their use of the

outside air as a heat source or sink. The higher temperature differential during periods of extreme cold

or heat leads to declining efficiency, as explained above. In mild weather, COP may be around 4.0, while

at temperatures below around −8 °C (17 °F) an air-source heat pump can achieve a COP of 2.5 or better,

which is considerably more than the energy efficiency that may be achieved by a 1980's heating systems,

and very similar to state of the art oil or gas heaters.[12] The average COP over seasonal variation is

typically 2.5-2.8, with exceptional models able to exceed 6.0 in very mild climate, but not in freezing

climates.[13]

Air source heat pumps for cold climates

At least two manufacturers are selling heat pumps that maintain better heating output at lower outside

temperatures than conventional air source heat pumps. These low temperature optimized models make air

source heat pumps more practical for cold climates because they don't freeze to a stop that quickly. Some

models however, defrost their outdoor unit electrically at regular intervals, which increases electricity

consumption dramatically during the coldest weeks. In areas where only one fossil fuel is currently

available (e.g. heating oil; no natural gas pipes available) these heat pumps could be used as an

alternative, supplemental heat source to reduce a building's direct dependence on fossil fuel. Depending

on fuel and electricity prices, using the heat pump for heating may be less expensive than fossil fuel. A

backup, fossil-fuel heat source may still be required for the coldest days.

The heating output of low temperature optimized heat pumps (and hence their energy efficiency) still

declines dramatically as the temperature drops, but the threshold at which the decline starts is lower

than conventional pumps, as shown in the following table (temperatures are approximate and may vary by

manufacturer and model):

Air Source Heat Pump Type Full heat output at or above this temperature Heat output down to 60%

of maximum at
Conventional 47 °F (8.3 °C) 17 °F (-8.3 °C)
Low Temp Optimized 14 °F (-10 °C) -13 °F (-25 °C)
Ground source heat pumps

Ground source heat pumps, which are also referred to as Geothermal heat pumps, typically have higher

efficiencies than air-source heat pumps. This is because they draw heat from the ground or groundwater

which is at a relatively constant temperature all year round below a depth of about thirty feet (9 m).

[14] This means that the temperature differential is lower, leading to higher efficiency. Ground-source

heat pumps typically have COPs of 3.5-4.0 at the beginning of the heating season, with lower COPs as heat

is drawn from the ground. The trade off for this improved performance is that a ground-source heat pump

is more expensive to install due to the need for the drilling of wells or digging of trenches in which to

place the pipes that carry the heat exchange fluid. When compared versus each other, groundwater heat

pumps are generally more efficient than heat pumps using heat from the soil. Ground sources tend to

accumulate cold, which is a significant problem if ground water is stagnant and they have been designed

to be just big enough. One way to fix cold accumulation, is to use ground water to cool the floors on hot

days. Another way is to make large solar collectors, for instance by putting plastic pipes just under the

roof, or by putting coils of black polyethylene pipes under glass on the roof, or by piping the tarmac of

the parking lot. The most cost effective way is to put a large air to water heat exchanger on the

rooftop.

Heat distribution

This section does not cite any references or sources. Please help improve this section by adding

citations to reliable sources. Unsourced material may be challenged and removed. (January 2011)
Heat pumps are only highly efficient when they distribute produced heat at a low temperature, ideally

around or below 32 °C (90 °F). Normal steel plate radiators are no good: they would need to have four

to six times their current size. Underfloor heating is the ideal solution. When wooden floors or carpets

would spoil their efficiency, wall heaters (plastic pipes covered with a thick layer of chalk) and piped

ceilings can be used. Both systems have the disadvantage that they are slow starters, and that they would

require extensive renovation in existing buildings. The alternative is a warm air system in which water

runs through a ventilator driven water to air heater. Such a thing can either complement floor heating

during warm up, or it can be a quick and economical way to implement a heat pump system into existing

buildings. Oversizing them reduces their noise. To efficiently distribute warm water or air from a heat

pump, water pipes or air shafts should have significantly larger diameters then in conventional systems,

and underfloor heaters should have much more pipes per square meter.

Solid state heat pumps

Main article: Magnetic refrigeration
In 1881, the German physicist Emil Warburg put a block of iron into a strong magnetic field and found

that it increased very slightly in temperature. Some commercial ventures to implement this technology are

underway, claiming to cut energy consumption by 40% compared to current domestic refrigerators.[15] The

process works as follows: Powdered gadolinium is moved into a magnetic field, heating the material by 2

to 5 °C (4 to 9 °F). The heat is removed by a circulating fluid. The material is then moved out of the

magnetic field, reducing its temperature below its starting temperature.

Main article: Thermoelectric materials
Solid state heat pumps using the Thermoelectric Effect have improved over time to the point where they

are useful for certain refrigeration tasks. Commercially available technologies have efficiencies that

are currently well below that of mechanical heat pumps, however this area of technology is currently the

subject of active research in materials science.

Main article: Thermoacoustic hot air engine
Near-solid-state heat pumps using Thermoacoustics are commonly used in cryogenic laboratories.[citation

needed]

History

This section requires expansion.
Milestones:

1748: William Cullen demonstrates artificial refrigeration.
1834: Jacob Perkins builds a practical refrigerator with diethyl ether.
1852: Lord Kelvin describes the theory underlying heat pump.
1855–1857: Peter Ritter von Rittinger develops and builds the first heat pump.[16]
See also

EcoCute domestic heat pump water heater
Flash evaporation
Geothermal heat pump
Heat exchanger
Renewable heat
Thermoelectric heat pumps that use the Peltier effect
Vapor-compression refrigeration
Vortex tube
IEA-ECBCS Annex 48 : Heat Pumping and Reversible Air Conditioning
References

^ The Systems and Equipment volume of the ASHRAE Handbook, ASHRAE, Inc., Atlanta, GA, 2004
^ Air-source heat pumps|url=http://www.nrel.gov/docs/fy01osti/28037.pdf
^ Jim O'brien - Inventor, Triea Systems (invalid reference - not WP:RS)
^ http://www.mecanica.pub.ro/frigo-eco/R404A_DME.pdf 101110
^ BSRIA, "European energy legislation explained", www.bsria.co.uk, May 2010.
^ a b c d The Canadian Renewable Energy Network 'Commercial Earth Energy Systems', Figure 29. . Retrieved

December 8, 2009.
^ Technical Institute of Physics and Chemistry, Chinese Academy of Sciences 'State of the Art of Air-

source Heat Pump for Cold Region', Figure 5. . Retrieved April 19, 2008.
^ a b SINTEF Energy Research 'Integrated CO2 Heat Pump Systems for Space Heating and DHW in low-energy

and passive houses', J. Steen, Table 3.1, Table 3.3. . Retrieved April 19, 2008.
^ http://www2.vlaanderen.be/economie/energiesparen/doc/brochure_warmtepomp.pdf
^ Homeowners using heat pump systems[dead link]
^ "Heat pumps sources including groundwater, soil, outside and inside air)" (PDF).

http://www2.vlaanderen.be/economie/energiesparen/doc/folder_warmtepomp.pdf. Retrieved 2010-06-02.
^ EnergyIdeas.org, "Product & Technology Review: Acadia Heat Pump", Table 1, Dec 2007.
^ "the IPCC 4th Working Group III report" (PDF). http://www.ipcc.ch/pdf/assessment-report/ar4/wg3/ar4-

wg3-chapter6.pdf. Retrieved 2010-06-02.
^ Earth Temperature and Site Geology, http://www.geo4va.vt.edu/A1/A1.htm
^ Guardian Unlimited, December 2006 'A cool new idea from British scientists: the magnetic fridge'
^ Banks, David L.. An Introduction to Thermogeology: Ground Source Heating and Cooling. Wiley-Blackwell.

ISBN 978-1-4051-7061-1.
External links

Wikimedia Commons has media related to: Heat pumps
Heat pump explanation - Information from Daikin on heat pump technology
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International Energy Agency Heat Pump Programme, Information site for heat pumping technology
Heat Pumps Long Awaited Way out of the Global Warming - Heat Pump & Thermal Storage Technology Center of

Japan
Heat Pumps the Trump Card in Fight against Global Warming - The Japan Journal, October 2006
Heating and Cooling with a Heat pump - Information from the Canadian Government's Natural Resources

Department, Office of Energy Efficiency
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